Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species
نویسنده
چکیده
Organic chemistry has mainly developed with the use of second-row elements such as carbon, oxygen, and nitrogen, while the synthesis and isolation of the heavier congeners of typical organic molecules as stable compounds has been a dream for organic chemists. Our main research interest is the elucidation of the similarities and differences in structures and reactivities between organic compounds and the corresponding heavier congeners. These studies are interesting and important from the standpoints of fundamental chemistry, and open the way to more extensive application of main group chemistry.
منابع مشابه
Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species.
Activation of dihydrogen by masked dialumenes (Al=Al doubly bonded species) is reported. Reactions of barrelene-type dialumanes, which have the reactivity as masked equivalents of 1,2-diaryldialumenes ArAl=AlAr, with H2 afforded dihydroalumanes ArAlH2 at room temperature (Ar: bulky aryl groups). These dihydroalumanes form hydrogen-bridged dimers [ArHAl(μ-H)]2 in the crystalline state, while a m...
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